Retreat to advance: self-blocking enables efficient mineral replacement

TL;DR

This study uses pore-network simulations to reveal how self-blocking in mineral replacement reactions can lead to more uniform mineral distribution by re-routing flow, contrasting with traditional wormhole formation.

Contribution

It introduces a new understanding of self-blocking regimes that enable efficient, uniform mineral replacement, supported by simulation-based analysis and design criteria.

Findings

Self-blocking leads to a mosaic of micro-fronts for uniform mineral distribution.

Two regimes identified: in situ replacement and exploratory re-routing.

Design criteria for achieving exploratory-mode behavior are derived.

Abstract

Mineral replacement reactions under advective flow often suffer from severe spatial inefficiency: dissolution causes the flow to self-focus into a few dominant wormholes that bypass the surrounding matrix, leaving most of the rock unreplaced. Here we show -- through two-dimensional pore-network simulations -- that replacement can be effective in two regimes. The first arises when the precipitation rate significantly exceeds the dissolution rate, leading to in situ replacement in which a uniform front of the secondary mineral advances through the matrix. The second, exploratory mode, occurs when the system repeatedly self-blocks and re-routes. In this regime, each channel lives only long enough to deliver reactant a short distance ahead of the front before its tip is cemented by the product phase; pressure re-routes through an adjacent corridor, and the cycle begins anew. Over time the replacement front advances as a mosaic of overlapping micro-fronts, distributing the secondary mineral almost uniformly. We derive design criteria for achieving exploratory-mode behaviour and discuss implications for both natural and engineered reactive-infiltration systems.