Thermodynamic accessibility of Li-Mn-Ti-O cation disordered rock-salt phases

TL;DR

This study maps the phase diagram of Li-Mn-Ti-O disordered rock-salt phases, revealing lower synthesis temperatures for certain compositions, which could improve Li-ion battery cathode manufacturing.

Contribution

It combines first-principles calculations and experiments to predict the phase stability and disorder temperatures across the Li-Mn-Ti-O system, guiding optimized synthesis conditions.

Findings

Disordered rock-salt phases are stable at lower temperatures (700-900°C) for specific compositions.

The phase diagram includes DRX, orthorhombic LiMnO2, and layered Li2Mn1-yTiyO3 phases.

Higher Mn4+ content leads to higher disorder temperatures and phase separation.

Abstract

Disordered rock-salt with Li-excess (DRX) cathode phases within the Li-Mn-Ti-O (LMTO) composition space have recently been extensively studied, as they promise to deliver exceptional energy density at low cost in Li-ion batteries. The continued development of LMTO DRX with improved power density and cycling stability requires optimization of the composition and particle size/morphology, which are determined by synthesis conditions such as annealing temperatures and hold times. These challenges motivate our investigation of the phase diagram of the LMTO rock-salt phase space, with a focus on understanding the stability of DRX by quantifying the order-disorder transition temperature ($T_\text{disord}$) as a function of composition. We harness first-principles calculations and X-ray diffraction experiments to establish the LMTO phase diagram, which lies within the LiMnO$_2$ -- Li$_2$MnO$_3$ -- Li$_2$TiO$_3$ pseudo-ternary. Our calculations predict that the LMTO phase diagram at elevated temperature ($700 - 1300$ C) is composed of three phases: DRX, orthorhombic LiMnO$_2$, and layered Li$_2$Mn$_\text{1-y}$Ti$_\text{y}$O$_3$ ($0 < \text{y} < 1$). $T_\text{disord}$ decreases significantly as off-stoichiometry is introduced to the end-point compositions, resulting in a eutectoid phase diagram. Importantly, a significant range of LMTO compositions containing small to moderate fractions of Li-excess and Ti doping (relative to LiMnO$_2$) have $T_\text{disord}$ spanning $700 - 900$ C. These temperatures are substantially lower than conventional DRX synthesis temperatures ($\geq 1000$ C), suggesting the promise of decreasing synthesis temperatures for specific DRX compositions. The compositions containing moderate to high fractions of Mn$^{4+}$ instead have much greater $T_\text{disord}$ and phase separation to layered Li$_2$MnO$_3$ becomes highly favored.