Single-Crystal Growth and Magnetic, Electronic Properties of the FCC Antiferromagnet Ba_2CoMoO_6

TL;DR

This study reports the growth and detailed analysis of the magnetic and electronic properties of Ba₂CoMoO₆ single crystals, revealing a $J_{eff} = 1/2$ ground state and potential for spintronic applications.

Contribution

It provides the first comprehensive characterization of BCMO's structure, magnetic behavior, and electronic structure, highlighting its $J_{eff} = 1/2$ state and strong spin-orbit coupling.

Findings

BCMO crystallizes in a face-centered cubic structure.

Antiferromagnetic order appears below 20.1 K.

Surface photovoltage shows a strong optical response at 2.65 eV.

Abstract

This work presents a comprehensive investigation of the structural, magnetic, and electronic properties of the double perovskite Ba$_2$CoMoO$_6$ (BCMO). Single crystals were grown via floating-zone and Czochralski techniques and characterized using a set of complementary methods. X-ray diffraction analysis confirmed that BCMO crystallizes in a face-centered cubic structure with space group $Fm\bar{3}m$. Magnetic susceptibility measurements reveal antiferromagnetic ordering below $T_\mathrm{N} = 20.1(1)$~K, with a spin-flop transition at $\mu_0 H = 2.65$~T. Heat-capacity measurements and entropy analysis, $\Delta S \approx 0.95\,R\ln 2$, are consistent with a $J_\mathrm{eff} = \tfrac{1}{2}$ effective ground state for Co$^{2+}$ ions. X-ray absorption spectroscopy at the Co~$L_{2,3}$ edges provides insight into the local electronic structure, revealing spin-orbit and crystal-field splitting effects; cluster-model calculations constrained by the XAS spectra yield a Land\'{e} $g$ factor $g = 4.52$, consistent with a spin-orbit-entangled $J_\mathrm{eff} = \tfrac{1}{2}$ ground state. Surface photovoltage spectroscopy reveals a strong optical response with a prominent feature at $2.65$~eV. These findings advance the understanding of face-centered cubic lattice antiferromagnets with strong spin-orbit coupling and suggest the technological promise of BCMO for spintronic and energy-conversion applications.