The JWST Early Release Science Program for Direct Observations of Exoplanetary Systems. VII. Molecular Mapping Performance with JWST/MIRI MRS: VHS 1256 b as a case study

TL;DR

This study demonstrates the effectiveness of molecular mapping via cross-correlation on JWST/MIRI MRS data to characterize exoplanet atmospheres, detecting key molecules and constraining atmospheric parameters.

Contribution

It introduces the application of molecular mapping with JWST/MIRI MRS to directly observe and analyze exoplanet atmospheres, including trace species and isotopic ratios.

Findings

Detected CO and H2O with high significance.

Measured NH3 abundance and isotopic ratios consistent with models.

Validated molecular mapping as a robust technique for exoplanet characterization.

Abstract

VHS 1256 b was the first planetary-mass companion to be observed with the James Webb Space Telescope's Mid-Infrared Instrument (JWST/MIRI) using the Medium-Resolution Spectrometer (MRS). The MRS provides high-quality integral-field spectral data in the mid-infrared (IR) wavelengths from 4.9 to 18 um. This dataset serves as a testbed for applying cross-correlation techniques to characterize exoplanet atmospheres. We implement the so-called molecular mapping approach, which consists of performing a spectral cross-correlation between each spectral pixel and atmospheric model templates. We compare these results with those obtained from cross-correlation of the extracted spectrum. Using a self-consistent Exo-REM atmospheric model grid, we constrain the temperature, surface gravity, C/O ratio, and metallicity, finding values consistent with those obtained from other analysis methods. We detect CO (S/N $\sim$ 25) and H2O (S/N $\sim$ 76), with tentative detections of NH3 and CH4 (S/N$\sim$ 3). We test cross-correlation to measure trace-species abundances and isotopic ratios. We measure a volume mixing ratio of [NH3] =-5.73^{+0.15}_{-0.14} and an isotopic ratio $^{12}\mathrm{C}/^{13}\mathrm{C}=77.8^{+13}_{-10}$, both consistent with free-chemistry retrievals. The derived NH3 volume mixing ratio, combined with the measured temperature and radius, is consistent with VHS 1256 b having a mass above the deuterium-burning limit. These results demonstrate the diagnostic power of mid-IR spectroscopy and highlight cross-correlation as a robust method for characterizing directly imaged exoplanets, even in future higher-contrast regimes where spectral extraction becomes challenging. Future MIRI MRS observations across a wider range of temperatures and masses will further expand our understanding of planetary atmospheric chemistry.