Discovery of a hybridization-wave electronic order in a van der Waals Kondo lattice

TL;DR

This study provides the first direct experimental evidence of a hybridization wave in a van der Waals Kondo lattice, revealing a novel quantum order with symmetry-breaking modulations in layered transition metal dichalcogenides.

Contribution

It demonstrates the real-space visualization of a hybridization wave in 6R-TaS2, confirming theoretical predictions and linking it to electronic nematic order.

Findings

Observation of hybridization gap in 1T-TaS2 layers

Detection of uniaxial unit-cell doubling modulation

Correlation between hybridization wave and nematic order

Abstract

Kondo lattice systems, in which localized magnetic moments coherently hybridize with itinerant electrons, exhibit a rich landscape of emergent quantum phenomena. Within this framework, the hybridization strength itself has been theoretically proposed as a spatially modulated order parameter, giving rise to a so-called hybridization wave. However, direct experimental evidence of this quantum state has remained an outstanding challenge. Here, we report the direct observation of a hybridization wave in the layered transition metal dichalcogenide 6R-TaS2, a naturally occurring heterostructure composed of alternating 1T- and 1H-TaS2 layers. Using scanning tunneling microscopy and spectroscopy (STM/STS), we identify the hybridization gap in 1T layer, demonstrating the establishment of a coherent Kondo lattice. Notably, we discover that the hybridization gap present a uniaxial unit-cell doubling modulation, which breaks the both translational and rotational symmetries of the underlying Star-of-David superlattice. Such unit-cell doubling is not caused by structural topography, and therefore, constitutes the real-space visualization of the hybridization-wave order. Furthermore, the hybridization wave correlates with an energy-dependent nematic order that shares the same periodicity and orientation, revealing intertwined electronic instabilities. Our findings not only validate a long-standing prediction but also establish layer-engineered van der Waals materials as a versatile platform for exploring and controlling hybridization-driven quantum phases.