Valley-dependent electron-phonon scattering in thermoelectric semimetal Ta$_2$PdSe$_6$

TL;DR

This study reveals that electron-phonon scattering in Ta$_2$PdSe$_6$ is strongly valley-dependent due to a soft phonon mode coupled with specific electronic bands, explaining its unique transport properties.

Contribution

It provides a microscopic understanding of valley-dependent electron-phonon scattering in Ta$_2$PdSe$_6$, highlighting the role of a soft phonon mode and intervalley scattering.

Findings

Soft phonon mode strongly coupled with valence band at $b3$ point.

Strong valley-dependent electron-phonon scattering observed.

Sharp change in electron self-energy near Fermi level for certain valleys.

Abstract

Quasi-one-dimensional transition-metal chalcogenide Ta$_2$PdSe$_6$ is a promising thermoelectric semimetal due to the strong electron-hole asymmetry in the carrier lifetime. However, the microscopic origin of such a strong asymmetry remains unclear. In this study, we theoretically investigate electron-phonon scattering in Ta$_2$PdSe$_6$. There is a soft phonon mode mainly consisting of atomic displacements in PdSe$_4$ chains. This soft mode is strongly coupled with the highest valence band at the $\Gamma$ point, which lies slightly below the Fermi energy, and causes strong electron-phonon scattering. The bottom of the electron pocket energetically overlapped with that band also suffers from strong intervalley scattering, by which the imaginary part of the electron self-energy exhibits a sharp change near the Fermi level. On the other hand, the imaginary part of the self-energy for carriers in the hole pocket shows a moderate energy dependence. Thus, we find that electron-phonon scattering is strongly valley-dependent. Our finding will help us to understand the distinctive transport properties observed in Ta$_2$PdSe$_6$.