A high-performance cobalt-free cathode for proton-conducting solid oxide fuel cells via multi-element doping in Sr2Fe2O6

TL;DR

This paper introduces a novel multi-element doped Sr2Fe2O6 cathode that significantly enhances performance and stability in proton-conducting solid oxide fuel cells, offering a cobalt-free, cost-effective alternative with superior electrochemical properties.

Contribution

The study develops and validates a multi-element doping strategy to improve Sr2Fe2O6 cathodes, achieving unprecedented power densities and stability in proton-conducting SOFCs.

Findings

SFO-ZSSM exhibits higher oxygen and proton transport kinetics.

Fuel cells with SFO-ZSSM reach peak power densities over 1500 mW/cm².

The doped cathode shows excellent operational stability over 100 hours.

Abstract

The development of efficient and stable intermediate-temperature solid oxide fuel cells (SOFCs) necessitates high-performance cathode materials that are cobalt-free, cost-effective, and compatible with proton-conducting electrolytes. While Sr2Fe2O6 (SFO)-based ferrites offer a promising cobalt-free alternative, their electrochemical performance requires further enhancement to compete with state-of-the-art cathodes. This study proposes and validates a multi-element doping strategy as a superior approach to tailor the properties of SFO. The specific oxide Sr2Fe1.5Mo0.125Sn0.125Sc0.125Zr0.125O6 (SFO-ZSSM) is designed, synthesized via a solid-state reaction method, and systematically evaluated as a cathode for proton-conducting SOFCs (H-SOFCs). Its performance is benchmarked against a series of SFO cathodes modified with single dopants (Mo, Sn, Sc, Zr). Structural characterization confirms the successful formation of a phase-pure perovskite structure with homogeneous elemental distribution. Electrical conductivity relaxation (ECR) measurements reveal that SFO-ZSSM exhibits dramatically enhanced oxygen and proton transport kinetics compared to all singly-doped counterparts, demonstrating a significant synergistic effect. Consequently, fuel cells employing the SFO-ZSSM cathode deliver exceptional peak power densities of 1580, 1137, and 854 mW cm-2 at 700, 650, and 600 {\deg}C, respectively, significantly outperforming cells with single-doped cathodes. Electrochemical impedance spectroscopy further corroborates its superior catalytic activity, showing the lowest polarization resistance. Moreover, the SFO-ZSSM cell demonstrates excellent operational stability over 100 hours, attributed to its robust microstructure and Ba-free composition.