A T-matrix scattering formalism for electron-beam spectroscopy

TL;DR

This paper introduces a T-matrix scattering formalism extended to electron-beam spectroscopy, enabling fast, accurate simulations of electron-induced light-matter interactions in complex nanophotonic structures.

Contribution

The authors develop and implement a T-matrix-based scattering framework for electron-beam spectroscopy, extending existing electromagnetic scattering tools to include fast electron interactions.

Findings

Validated on various nanostructures including nanodisks and nanospheres.

Provides a computationally efficient tool for cathodoluminescence and EELS simulations.

Available as open-source software for the research community.

Abstract

Advanced computational tools that describe the interaction of electrons with structured nanophotonic materials are crucial for theoretical predictions, specific design tasks, and the interpretation of experimental results. These tools open the door to systematic exploration of free-electron-driven nanophotonic light sources, among others. Here, we report on the implementation of electron-beam spectroscopy in a T-matrix-based scattering formulation. Such a framework is quite versatile in predicting the electromagnetic response of complex photonic materials composed of periodically or aperiodically arranged individual scatterers. By extending this formalism to describe interactions with fast electrons, we provide a fast and accurate numerical tool for simulating cathodoluminescence (CL) and electron energy-loss spectroscopy (EELS) measurements. The desired functionalities are implemented into the existing software suite treams for electromagnetic scattering computations, and the extended code treams_ebeam is available online at https://github.com/tfp-photonics/treams_ebeam. We demonstrate the implementation details on a carefully selected set of problems, including single scatterers of various shapes and materials, a periodic chain of elliptical nanodisks, and a finite cluster of nanospheres arranged in a two-dimensional (2D) lattice. By uniting fast-electron physics with advanced scattering theory, our framework unlocks new possibilities for designing, understanding, and engineering next-generation nanoscale light-matter interactions.