Chemistry in the High expansion-velocity C-rich evolved star AFGL2233. Isotopic ratios, peculiarities and evolutionary status

TL;DR

This study characterizes the chemical composition and isotopic ratios of the high-velocity, carbon-rich evolved star AFGL2233, revealing peculiar molecular abundances and suggesting a complex evolutionary history involving nucleosynthesis and possible binarity.

Contribution

It provides the first comprehensive molecular inventory and isotopic analysis of AFGL2233, highlighting its unique chemical peculiarities and evolutionary implications.

Findings

High NH3, H2O, and SiN abundances detected

Isotopic ratios vary significantly among species

Evidence suggests N-enrichment and possible binary influence

Abstract

High expansion velocity carbon stars (HVCs) are a rare class of evolved stars whose circumstellar envelopes (CSEs) combine C-rich chemistry with unusually high expansion velocities typical of O-rich massive evolved stars. AFGL2233 has been proposed as a high-mass evolved object that exhausted hot-bottom burning. Studying its chemistry is essential to understand the nature and evolution of these objects. We characterize the chemical composition and isotopic ratios of the CSE of AFGL2233 and investigate chemical peculiarities, including the presence of N- and O-bearing species in a C-rich environment. We carried out a complete line survey at 3 mm and 1 mm using the IRAM 30m telescope, complemented by Herschel/HIFI FIR observations and interferometric maps of SiO, C2H, and HCN. Molecular emission was analyzed using rotational diagrams and radiative transfer modeling under the LVG approximation. Column densities and fractional abundances were derived for more than 30 molecular species, including isotopologues, and compared with other evolved stars. The Gaia DR3 distance of 1.236 kpc implies a luminosity of ~2 Lsun, consistent with an initial mass of 4.5-9 Msun. The molecular inventory confirms C-rich chemistry but reveals unusually high abundances of NH3, H2O, and SiN. The isotopic ratios vary among species, with 12C/13C ranging from 7 to 55. The C2H/C4H ratio is abnormally high compared with C-rich AGB stars. The presence of SiN and high NH3 may indicate N-enrichment or the influence of a companion. AFGL2233 is likely a high-mass AGB or super-AGB star with a complex evolutionary history involving nucleosynthesis, shocks, and possible binary interaction.