Spatial distribution of organics in the Horsehead nebula: Signposts of chemistry driven by atomic carbon

TL;DR

This study maps the distribution of organic molecules at the UV-illuminated edge of the Horsehead nebula, revealing that UV-driven processes and grain-surface chemistry significantly influence organic molecule formation in PDRs.

Contribution

It provides the first detailed spatial analysis of organic molecules in the Horsehead nebula's PDR, highlighting the role of atomic carbon and photodissociation in organic chemistry.

Findings

Most organics are enhanced at the UV edge, indicating surface chemistry driven by atomic carbon.

HC3N and CH3OH show different behaviors, suggesting inefficient formation or desorption.

Gas-phase photochemistry may also contribute to organic molecule production.

Abstract

(Abridged) Complex organic molecules (COMs) are considered essential precursors to prebiotic species. While COMs were once expected to be efficiently destroyed under UV-irradiated conditions, detections in photodissociation regions (PDRs) have challenged this view. However, the mechanisms by which UV radiation contributes to their formation are still uncertain. Here, we present moderately resolved maps of simple and complex organic molecules at the UV-illuminated edge of the Horsehead nebula, obtained by combining ALMA and IRAM 30m single-dish observations at $\sim 15^{\prime\prime}$ resolution. We analyze the spatial distribution of species such as C$^{17}$O, CH$_2$CO, CH$_3$CHO, HNCO, CH$_3$CN, and HC$_3$N. By incorporating previous C$^{17}$O and C$^{18}$O single-dish data as well as PdBI maps of H$_2$CO and CH$_3$OH, we derive profiles of gas density, temperature, thermal pressure, and column densities of the organic species as a function of distance from the UV source. Our results show that most organic species$-$particularly H$_2$CO, CH$_2$CO, CH$_3$CHO, HNCO, and CH$_3$CN$-$exhibit enhanced column densities at the UV-illuminated edge compared to cloud interiors, possibly indicating efficient dust-grain surface chemistry driven by the diffusion of atomic C and radicals produced via photodissociation of CO and CH$_3$OH, as supported by recent laboratory experiments. The exceptions, HC$_3$N and CH$_3$OH, can be attributed to inefficient formation on dust grains and ineffective non-thermal desorption into the gas phase, respectively. Additionally, contributions from gas-phase hydrocarbon photochemistry, possibly seeded by grain-surface products, cannot be ruled out. Further chemical modeling is needed to confirm the efficiency of these pathways for the studied species, which could have important implications for other cold, UV-irradiated environments such as protoplanetary disks.