Embedded Ferroelectric Nanoclusters can drive Polarization Reversal in a Non-Ferroelectric Polar Film via the Proximity Effect

TL;DR

This study demonstrates that embedded ferroelectric nanoclusters can induce polarization reversal in non-ferroelectric AlN films through the proximity effect, lowering switching fields and enabling new device functionalities.

Contribution

It introduces a thermodynamic and finite element modeling approach to show how nanocluster shape influences polarization switching in non-ferroelectric films via the proximity effect.

Findings

Nanocluster shape affects polarization switching behavior.

Proximity effect reduces coercive fields significantly.

Localized reversed polarization domains form at interfaces.

Abstract

Heterogeneous nucleation from defects dominates the electric field required for polarization switching of ferroelectrics. Here, we consider the switching of a nominally non-switchable polar thin film of AlN due to the proximity effect arising from embedded ferroelectric nanoclusters of Al1-xScxN. Using a Landau-Ginzburg-Devonshire thermodynamic approach and finite element modeling, we study the influence of nanocluster shape on polarization switching and domain nucleation emerging in AlN. The ferroelectric nanocluster boundary is modeled as a thin layer transitioning from Al1-xScxN to AlN. We analyze the conditions under which polarization switching in the AlN film occurs at coercive fields significantly lower than its dielectric breakdown field. In the presence of spike-like Al1-xScxN nanoclusters, the proximity effect enables switching of the spontaneous polarization in AlN and significantly reduces the corresponding coercive field. The internal field, which is depolarizing inside the AlN (due to its larger spontaneous polarization) and polarizing within the ferroelectric Al1-xScxN nanoclusters (due to its smaller spontaneous polarization), lowers the potential barrier in the clusters and nucleates nanodomains at the Al1-xScxN-AlN interface, forming localized regions of reversed polarization. Proximity effect can thus provide a pathway towards "thawing" previously "frozen" ferroelectrics through engineered nucleation for memory, actuation and optical technologies.