Crystal growth and characterization of a hole-doped iron-based superconductor Ba(Fe$_{0.875}$Ti$_{0.125}$)$_2$As$_2$

TL;DR

This paper reports the growth and characterization of a new hole-doped iron-based superconductor Ba(Fe$_{0.875}$Ti$_{0.125}$)$_2$As$_2$, demonstrating superconductivity at 17.5 K and providing insights into hole doping effects.

Contribution

The study introduces a novel hole-doped superconductor Ba(Fe$_{0.875}$Ti$_{0.125}$)$_2$As$_2$ and explores its properties, expanding the understanding of doping effects in iron-based superconductors.

Findings

Superconductivity observed at $T_{c0} \\approx 17.5$ K.

Positive Hall coefficient indicating hole doping.

Density functional theory suggests hole pockets from Fe/Ti 3$d$ orbitals.

Abstract

We report the crystal growth of a new hole-doped iron-based superconductor Ba(Fe$_{0.875}$Ti$_{0.125}$)$_2$As$_2$ by substituting Ti on the Fe site. The crystals are accidentally obtained in trying to grow Ni doped Ba$_2$Ti$_2$Fe$_2$As$_4$O. After annealing at 500 \textcelsius $ $ in vacuum for one week, superconductivity is observed with zero resistance at $T_{c0} \approx 17.5$ K, and about 20\% diamagnetic volume down to 2 K. While both the small anisotropy of superconductivity and the temperature dependence of normal state resistivity are akin to the electron doped 122-type compounds, the Hall coefficient is positive and similar to the case in hole-doped Ba$_{0.9}$K$_{0.1}$Fe$_2$As$_2$. The density functional theory calculations suggest dominated hole pockets contributed by Fe/Ti 3$d$ orbitals. Therefore, the Ba(Fe$_{1-x}$Ti$_{x}$)$_2$As$_2$ system provides a new platform to study the superconductivity with hole doping on the Fe site of iron-based superconductors.