A non-equilibrium strategy for the general synthesis of single-atom catalysts

TL;DR

This paper introduces a scalable, non-equilibrium ion implantation method for synthesizing single-atom catalysts, achieving high atom stability and exceptional catalytic performance for energy conversion.

Contribution

It presents a novel ion implantation strategy for scalable, precise synthesis of single-atom catalysts, bridging fundamental design and industrial manufacturing.

Findings

Successfully synthesized 36 SACs with ion implantation.

Pt/MoS2 shows low overpotential of 26 mV at 10 mA/cm².

SACs exhibit superior stability and performance over commercial catalysts.

Abstract

Single-atom catalysts (SACs) maximize atom efficiency and exhibit unique electronic structures, yet realizing precise and scalable atomic dispersion remains a key challenge. Here, we report a non-equilibrium strategy for the scalable synthesis of SACs via ion implantation, enabling precise stabilization of metal atoms on diverse supports. Using an industrial-grade ion source, wafer-scale ion implantation with milliampere-level beam currents enables high-throughput fabrication of SACs, while the synergistic energy-mass effects stabilize isolated metal atoms in situ. A library of 36 SACs was constructed, and the resulting Pt/MoS2 exhibits outstanding hydrogen evolution performance with an overpotential of only 26 mV at 10 mA cm-2 and exceptional long-term stability, surpassing commercial Pt/C. This work demonstrates ion implantation as a versatile platform bridging fundamental SACs design and scalable manufacturing, providing new opportunities for high-performance catalysts in energy conversion applications.