Updated Metallicity Diagnostics for Precision Oxygen Abundance Measurements in High-redshift Galaxies with JWST

TL;DR

This paper develops new metallicity diagnostics for high-redshift galaxies using JWST data, incorporating ionization and nitrogen effects to improve oxygen abundance measurements and understand cosmic chemical evolution.

Contribution

It introduces updated indicators that explicitly include ionization and nitrogen proxies, significantly improving the accuracy of metallicity estimates in high-redshift galaxies.

Findings

Updated indicators tighten the correlation with true oxygen abundance.

Calibration achieves R^2 > 0.5, up to 0.7 at z>2.

Reveals redshift evolution in metallicity diagnostics near cosmic noon.

Abstract

Recent work has demonstrated that widely used strong-line oxygen abundance indicators, such as O3N2, $\rm R23$, and $\widehat{\rm R}$, suffer from large uncertainties when applied to high-redshift galaxies. We show that this loss of precision primarily arises because, at fixed \Oabund, galaxies span a wide dynamic range in ionization parameter and nitrogen enrichment. Here we develop updated indicators that explicitly incorporate both effects via the proxies O32 and N2O2. We define ${\rm R}_{\rm u}\equiv \rm R23+\alpha_1 O32+\alpha_2 N2O2$, $\widehat{\rm R}_{\rm u}\equiv \rm \widehat{R}+\beta_1 O32+\beta_2 N2O2$, and ${\rm O}_{\rm u}\equiv \rm O3N2+\gamma_1 O32+\gamma_2 N2O2$, and calibrate \Oabund~as low-order polynomials in each composite indicator. Applied to a JWST sample with $T_{\rm e}$-method abundances, the updated indicators substantially tighten the correlations with \Oabund, boosting adjusted coefficients of determination from $\mathbb{R}^2\lesssim 0$ (classical indicators) to $\mathbb{R}^2\gtrsim 0.5$ for the full sample and to $\sim 0.7$ at $z>2$. The residuals reveal a redshift evolution in the mapping between \Oabund, strong lines, ionization, and nitrogen enrichment, with a pivotal turning point near the cosmic noon ($z\sim 2$). Our calibrations provide a practical, physically grounded path to precise metallicity measurements in the JWST era and a firmer basis for quantifying early chemical enrichment and feedback.