Ferroelectric polarization mapping through pseudosymmetry-sensitive EBSD reindexing

TL;DR

This paper introduces a novel EBSD reindexing technique that maps local ferroelectric polarization directions in polycrystalline materials, overcoming previous limitations in three-dimensional polarization mapping.

Contribution

The authors develop a pseudosymmetry-sensitive EBSD reindexing method with advanced processing and a new confidence index, enabling polarization mapping in materials with close crystallographic pseudosymmetries.

Findings

Successfully distinguished six polarization directions in ferroelectric materials.

Enhanced EBSD techniques applicable to materials with pseudosymmetries.

Extended EBSD capabilities to local polarization mapping in polycrystals.

Abstract

Ferroelectric materials exhibit a switchable, spontaneous polarization at the unit cell level--an attractive property utilized in many emerging technologies including, among others, high-density memory storage, low-power transistors, and high-speed fiber optic communication. Understanding the local polarization switching behavior, through domain nucleation and evolution, is critical to advancing these technologies and requires characterization of the local domain microstructure. However, in application-relevant polycrystalline materials exhibiting a distribution of grain orientations, a direct mapping of the polarization direction in three dimensions has remained inaccessible using conventional experimental approaches. Here, taking barium titanate single crystals and lead zirconium titanate polycrystals as our bulk model systems, we map the local polarization directions using a new electron backscatter diffraction indexing technique based on simulated pattern-matching. Through improved pre-processing techniques (including optimized pattern processing, a new pseudosymmetry-sensitive neighbor pattern averaging method, and DIC-based global sample-detector geometry calibration) and a new pseudosymmetry confidence index (which considers not only pattern similarity but pattern dissimilarity trends with other domain variant patterns), we successfully distinguish between the six polarization directions, despite the challengingly small unit cell aspect ratio of the selected materials. The methods developed in this work are not only applicable to ferroelectrics but any material which exhibits close crystallographic pseudosymmetries--extending the current capabilities of EBSD.