Detecting the Onset and Progression of Spinodal Decomposition using Transient Grating Spectroscopy

TL;DR

This study demonstrates that transient grating spectroscopy can non-destructively detect spinodal decomposition in Fe-Cr alloys by measuring elastic modulus changes, providing a rapid method for early materials degradation detection.

Contribution

The paper introduces the use of transient grating spectroscopy to detect spinodal decomposition through modulus stiffening, offering a novel, non-destructive testing approach.

Findings

Spinodal decomposition causes elastic modulus stiffening in Fe-Cr alloys.

TGS can detect spinodal decomposition before catastrophic degradation.

Elastic modulus non-linearity is key to detection.

Abstract

Spinodal decomposition can degrade corrosion resistance and embrittle materials. The ability to quickly, conclusively, and non-destructively detect the onset of spinodal decomposition before catastrophic materials degradation would represent a significant advance in materials testing. We demonstrate that spinodal decomposition can be detected in binary Fe-Cr alloys via modulus stiffening using in situ and ex situ transient grating spectroscopy (TGS). The key mechanistic insight is the non-linearity in elastic moduli as function of Cr content renders a spinodally decomposed Fe-Cr alloy stiffer than an equivalent solid solution for a certain range of initial chromium compositions. We confirm the presence of spinodal decomposition in the 36 at.% chromium alloy using differential scanning calorimetry (DSC), linked to known spinodal decomposition energetics, and show via atomistic simulations that elastic modulus stiffening is expected after spinodal decomposition in the 36 at.% chromium alloy. The results of this study suggest the potential use of TGS as a practical tool for non-destructive evaluation of key materials susceptible to such degradation.