Kinetic Flux Equations for Ion Exchange in Silicate Glasses

TL;DR

This paper refines and unifies ion exchange kinetic flux equations for silicate glasses, incorporating mechanical stress effects and thermodynamic consistency to improve understanding of ion transport phenomena.

Contribution

It provides a systematic, physically consistent formulation of ion exchange equations, extending classical models by including stress effects and cross-term interactions.

Findings

Enhanced theoretical framework for ion exchange in silicate glasses.

Inclusion of mechanical stress effects on ion transport.

Improved predictive capability for ion exchange kinetics.

Abstract

Ion exchange kinetic flux equations have been extensively investigated since the mid-twentieth century and continue to provide a fundamental framework for describing mass transport phenomena in solid materials. Despite the maturity of this field, inconsistencies remain in the literature concerning the definition, dimensional consistency, and physical interpretation of the parameters involved. A rigorous and unified treatment of these equations is therefore essential to ensure the reproducibility and comparability of theoretical and experimental studies. The present study aims to establish a coherent and systematic development of ion exchange kinetic flux equations, with particular emphasis on the consistent definition and dimensional formulation of the relevant physical quantities. Beyond refining the theoretical foundations, this study extends the classical formulation by incorporating the influence of mechanical stress on ion transport and considering cross-term interactions within the framework of linear irreversible thermodynamics. This study investigates ion-exchange kinetics within silicate glasses, operating under the Nernst-Planck binary interdiffusion regime. These developments provide a more comprehensive description of ion exchange kinetics, particularly as applied to silicate glasses, where coupling between chemical and mechanical effects plays a crucial role in determining transport behavior and performance.