High-Resolution Spectroscopy of the X-A Transition of the Carbon Monoxide Dication CO$^{2+}$

TL;DR

This study presents high-resolution rovibronic spectra of the CO$^{2+}$ dication, revealing spin-orbit splittings and providing detailed spectroscopic data that enhance understanding of this doubly charged molecular ion.

Contribution

The paper provides the first high-resolution spectra of CO$^{2+}$ rovibronic transitions, guided by ab initio calculations, and resolves spin-orbit splittings in the ground state.

Findings

Resolved spin-orbit splittings of the ground state

Achieved unprecedented spectral resolution for CO$^{2+}$

Expanded knowledge of doubly charged molecular ions

Abstract

We report rovibronic spectra of the A $^3\Sigma^+$($v'=0-2$) - X $^3\Pi_\Omega(v=0)$ rovibronic transitions ($|\Omega|=0, 1$ and 2) of the CO$^{2+}$ doubly-charged molecular ion. Spectra were recorded at high resolution ($\sim 5$~cm$^{-1}$) in a fast beam of CO$^{2+}$ molecules by detecting the Coulomb explosion of the molecules upon excitation to the A state. Measurements were guided by \textit{ab initio} calculations which then assisted the assignment of the observed spectral features. Our results resolve the spin-orbit splittings of the ground vibronic state X $^3\Pi_\Omega(v=0)$, but not the rotational structure of the bands due to spectral congestion, and provide spectroscopic information on CO$^{2+}$ with unprecedented resolution. In doing so they expand our knowledge of this benchmark doubly charged molecular ion and expand the short list of doubly charged molecules studied at high resolution.