Common sublattice-pure van Hove singularities in the kagome superconductors $\textit{A}$V$_{3}$Sb$_{5}$ ($\textit{A}$ = K, Rb, Cs)

TL;DR

This study reveals universal sublattice-pure van Hove singularities in kagome superconductors A V3Sb5, linking hybridization-driven VHSs to charge density wave order and electronic instabilities.

Contribution

It uncovers common sublattice-pure VHSs in A V3Sb5 driven by hybridization, providing a unified understanding of their electronic instabilities and exotic orders.

Findings

Identification of multiple VHSs near E_F from ARPES data

Discrepancies between experimental results and DFT predictions

VHSs arising from V-d and Sb-p hybridization promote charge order

Abstract

Kagome materials offer a versatile platform for exploring correlated and topological quantum states, where van Hove singularities (VHSs) play a pivotal role in driving electronic instabilities, exhibiting distinct behaviors depending on electron filling and interaction settings. In the recently discovered kagome superconductors $\textit{A}$V$_{3}$Sb$_{5}$ ($\textit{A}$ = K, Rb, Cs), unconventional charge density wave order, superconductivity, and electronic chirality emerge, yet the nature of VHSs near the Fermi level ($\textit{E}$$_{F}$) and their connection to these exotic orders remain elusive. Here, using high-resolution polarization-dependent angle-resolved photoemission spectroscopy, we uncover a universal electronic structure across $\textit{A}$V$_{3}$Sb$_{5}$ that is distinct from density-functional theory predictions that show noticeable discrepancies. We identify multiple common sublattice-pure VHSs near $\textit{E}$$_{F}$, arising from strong V-$\textit{d}$/Sb-$\textit{p}$ hybridization, which significantly promote bond-order fluctuations and likely drive the observed charge density wave order. These findings provide direct spectroscopic evidence for hybridization-driven VHS formation in kagome metals and establish a unified framework for understanding the intertwined electronic instabilities in $\textit{A}$V$_{3}$Sb$_{5}$.