Mesoporous Thin Films as Nanoreactors for Complex Oxide Nanoparticle-based Devices

TL;DR

This paper demonstrates a novel method to synthesize complex oxide nanoparticles within mesoporous thin films, enabling controlled fabrication of nanostructures for advanced electronic and energy devices.

Contribution

It introduces a new approach combining mesoporous thin films and oxide nanoparticles, with controlled filling and characterization, for device applications.

Findings

Successful synthesis of La0.88Sr0.12MnO3 inside mesoporous SiO2

Controlled pore filling with accessible porosity confirmed by X-ray reflectometry

Magnetic properties indicate weakly interacting ferromagnetic nanoparticles

Abstract

We combine for the first time the properties of ordered mesoporous thin films and complex oxide nanoparticles in the design of new heterostructures, taking advantage of the accessible tridimensional pores network. In this work, we demonstrate the feasibility of synthesizing La0.88Sr0.12MnO3 inside the pores of a mesoporous SiO2 thin film, using pulsed laser deposition. In order to understand the filling process, a set of samples were deposited for three different deposition times, on mesoporous and non-mesoporous SiO2 substrates. Their structural, magnetic, magnetocaloric and electrical transport properties were studied. All the results evidence the presence of the manganite compound inside the pores, which was confirmed by cross-section elemental mapping. X-ray reflectometry shows that it is possible to control the filling of the pores, keeping some accessible porosity. The magnetic behavior suggests the presence of weakly interacting ferromagnetic nanoparticles inside the pores. We provide here a successful strategy for the fabrication of complex oxide nanoparticles arrays with highly controlled size and ordering. Their easy incorporation into micro and nanofabrication procedures unveils direct implications in the field of interfaces and nanoparticle devices as diverse as energy conversion systems, solid oxide fuel cells, spintronics and neuromorphic memristor networks.