Ultraslow optical centrifuge with arbitrarily low rotational acceleration

TL;DR

This paper presents a novel laser pulse shaper that creates an ultraslow optical centrifuge with extremely low rotational acceleration, enabling precise control of molecular rotation in viscous media.

Contribution

The authors design and demonstrate an ultraslow optical centrifuge with tunable low angular acceleration, significantly lower than conventional designs, for controlling molecular rotation.

Findings

Achieved rotational accelerations three orders of magnitude lower than traditional centrifuges.

Successfully spun CS₂ molecules using the ultraslow centrifuge.

Demonstrated precise control of molecular rotation in viscous environments.

Abstract

We outline the design and characterization of a laser pulse shaper, which creates an ``ultraslow optical centrifuge'' - a linearly polarized field whose polarization vector rotates with arbitrarily low angular acceleration. By directly recording this rotation in time with nonlinear cross-correlation, we demonstrate the tunability of such centrifuge (both in terms of its initial and its final rotational frequencies) in the range of accelerations which are three orders of magnitude lower than those available with a conventional centrifuge design. We showcase the functionality of the ultraslow centrifuge by spinning CS$_2$ molecules in a molecular jet. Utilizing the extremely low angular acceleration to control molecular rotation inside viscous media is a promising application for this unique optical tool.