Interfacial Polarons Driven by Charge Transfer In WSe2/Cuprate Superconductor Systems

TL;DR

This study investigates how charge transfer at the WSe2/LSCO interface creates interfacial polarons, affecting electronic structures and potentially influencing high-temperature superconductivity in cuprates.

Contribution

It reveals the formation of interfacial small polarons driven by charge transfer in WSe2/LSCO heterostructures using spectroscopy and theoretical calculations.

Findings

Interfacial polarons are formed at the WSe2/LSCO interface.

Structural phase transition reduces electron-hole interaction in WSe2.

Special electronic band structure is observed due to interfacial effects.

Abstract

Understanding the electronic properties of doped copper-oxygen planes remains a significant challenge in condensed matter physics and is crucial to unraveling the mechanisms behind high-temperature superconductivity in cuprates. Recently, the observation of charge transfer and interfacial polarons in superconducting interface has aroused extensive research interest. However, experimental data to investigate charge transfer on the CuO2 plane and the presence of polarons are still missing. Here we conduct extensive research on the optical and electronic properties of two-dimensional material supported on copper-based superconductors. Unlike monolayer-WSe2 on other substrates, monolayer-WSe2 on La1.85Sr0.15CuO4 (WSe2/LSCO) produces a special band structure. Using high-resolution spectroscopic ellipsometry and density functional theory calculation methods, the special electronic structure can be attributed to the formation of the interfacial small polaron at the WSe2/LSCO interface which is driven by charge transfer between the CuO2 plane of the cuprate superconductor and WSe2. In addition, the structural phase transition of the LSCO substrate was observed to reduce the electron-hole (e-h) interaction of WSe2. These findings may spur future investigations on the effect of the interfacial polaron on the superconductivity of cuprates, and highlight the significant influence of interface effects on the electronic structure of WSe2 films. It provides an effective method to further explore the intrinsic relationship between interfacial polarons and superconductivity.