Real-space Atomic Dynamics in Liquid Gallium Studied by Inelastic Neutron Scattering

TL;DR

This study uses inelastic neutron scattering to investigate atomic dynamics in liquid gallium, revealing two distinct medium-range orders driven by density waves, which enhances understanding of liquid metal behavior.

Contribution

It introduces a novel application of inelastic neutron scattering to characterize real-space atomic dynamics and identifies two dynamical medium-range orders in liquid gallium.

Findings

Discovery of two dynamical medium-range orders in liquid gallium.

Identification of density waves driven by ionic and electronic interactions.

Linking atomic dynamics to electronic-state fluctuations in complex liquids.

Abstract

Gallium is a prototypical liquid metal and has gained renewed attention due to its unique properties. Characterizing and elucidating its atomic dynamics remains elusive despite numerous studies, primarily due to the challenges of quantifying atomic-scale dynamics in liquids. Recent developments in inelastic neutron scattering enable us to measure the Van Hove correlation function that describes the real-space motion of liquid atoms. In this work, we use this approach to reveal the dynamics in gallium liquids and find the co-existence of two dynamical medium-range orders (MROs), which have a dynamical behavior distinct from that of the short-range order (SRO). We propose that these MROs are driven by global forces in the form of two density waves, as a direct consequence of the underlying competition between ionic core repulsion and valence electron cohesion. We suggest that the density wave approach is not only applicable to other metallic liquids exhibiting similar structural anomalies, but also offers a promising direction for elucidating the dynamics of complex liquids and glasses by linking electronic-state fluctuations to atomic dynamics.