Chemical complexity in star formation induced by stellar feedback: cores shock-formed by the supernova remnant W44

TL;DR

This study investigates the chemical complexity in a shock-impacted region near SNR W44, revealing the presence of complex organic molecules and deuterated species, suggesting early-stage star formation influenced by supernova shocks.

Contribution

First detection of complex organic molecules in a supernova remnant-cloud interaction site, providing insights into chemical conditions of shock-induced star formation.

Findings

Detection of multiple deuterated molecules and COMs with low excitation temperatures.

Chemical abundances similar to low-mass starless cores and comets.

Clump is an early-stage, shock-induced low-mass star forming region.

Abstract

Low-velocity shocks from Supernova Remnants (SNRs) may set the physical and chemical conditions of star formation in molecular clouds. Recent evidence suggests that the Sun might have formed through this process. However, the chemical conditions of shock-induced star forming region remain poorly constrained. We study the chemical complexity of a shock-impacted clump, with potential to yield star formation, named the Clump, and located at the interface between the SNR W44 and the infrared dark cloud G034.77-00.55. We test whether the Clump has chemical properties consistent with those observed in star forming regions unaffected by SNRs. We use high-sensitivity, broad spectral surveys at 3 and 7 mm obtained with the 30m antenna at IIRAM and the 40 m YEBES antenna, to identify D-bearing species and complex organic molecules (COMs) toward the Clump. For all species, we estimate molecular abundances and compare them with those observed across star forming regions at different evolutionary stages and masses, as well as comets. We detect multiple deuterated molecules (DCO+, DNC, DCN, CH2DOH) and COMs (CH3OH, CH3CHO, CH3CCH, CH3CN, CH3SH) with excitation temperatures of 5-13 K. To the best of our knowledge, this is the first detection of COMs toward a site of SNR-cloud interaction. The derived D/H ratios (0.01-0.04) and COM abundances are consistent with those reported toward typical low-mass starless cores and comparable to cometary values. The overall level of chemical complexity is relatively low, in line with an early evolutionary stage. We suggest that the Clump is a early stage shock-induced low-mass star forming region, not yet protostellar. We speculate that SNR shocks may set the physical and chemical conditions to form stars. The resulting chemical budget may be preserved along the formation process of a planetary system, being finally incorporated into planetesimals and cometesimals.