Sub Band Gap Operation Limits for Perovskite Light Emitting Diodes

TL;DR

This paper investigates the fundamental limits and optimization strategies for operating perovskite LEDs below their band gap voltage, aiming to achieve high radiance with minimal power consumption.

Contribution

It provides a comprehensive analysis of sub band gap operation limits for PeLEDs, interpreting experimental data and proposing optimization routes for high radiance at low voltages.

Findings

Maximum EQE and ECE can be achieved at sub band gap voltages.

Identifies key factors limiting low voltage operation.

Suggests pathways to optimize PeLED performance at low bias.

Abstract

Ultra low voltage operation of Perovskite light emitting diodes (PeLEDs) has been demonstrated in recent years as high radiance with minimal power consumption is a desired feature. However, the light output at such conditions from PeLEDs is typically very low, and the maximum in external quantum efficiency (EQE) and energy conversion efficiency (ECE) are achieved at large biases with significant power consumption. Here, we explore the possibility of achieving maximums in EQE and ECE at sub band gap voltages for PeLEDs. Our analysis consistently interprets otherwise scattered experimental data from literature, identifies the limits for low voltage operation, and elucidates optimization routes for sub band gap high radiance operation of PeLEDs.