Hybrid VQE-CVQE algorithm using diabatic state preparation

TL;DR

This paper introduces a hybrid quantum algorithm combining VQE and CVQE techniques with diabatic state preparation, demonstrating high-accuracy energy calculations on simulated quantum systems.

Contribution

It presents a novel hybrid VQE-CVQE algorithm utilizing diabatic state preparation, applicable to both near-term and error-corrected quantum computers.

Findings

Achieved chemical accuracy in energy calculations on IBM Brisbane simulations.

Demonstrated applicability to systems of interacting electrons.

Suitable for implementation on various quantum hardware scales.

Abstract

We propose a hybrid variational quantum algorithm that has variational parameters used by both the quantum circuit and the subsequent classical optimization. Similar to the Variational Quantum Eigensolver (VQE), this algorithm applies a parameterized unitary operator to the qubit register. We generate this operator using diabatic state preparation. The quantum measurement results then inform the classical optimization procedure used by the Cascaded Variational Quantum Eigensolver (CVQE). We demonstrate the algorithm on a system of interacting electrons and show how it can be used on long-term error-corrected as well as short-term intermediate-scale quantum computers. Our simulations performed on IBM Brisbane produced energies well within chemical accuracy.