Helix alignment, chevrons, and edge dislocations in twist-bend ferroelectric nematics

TL;DR

This paper investigates surface alignment, chevron defects, and edge dislocations in twist-bend ferroelectric nematic liquid crystals, revealing unique defect behaviors and elastic properties relevant for electro-optical device applications.

Contribution

It provides the first detailed analysis of dislocation cores, chevron defect formation, and elastic characteristics in twist-bend ferroelectric nematics, highlighting their distinct defect dynamics.

Findings

Chevron defects form in planar cells of NTBF.

Dislocation cores do not split into semi-integer disclinations.

Dislocation climb shows high mobility, enabling temperature-dependent pitch adjustment.

Abstract

We explore surface alignment and edge dislocations in the recently discovered twist-bend ferroelectric nematic, NTBF, in which the vector of spontaneous polarization follows an oblique helicoidal trajectory around a polar twist-bend axis. In a planar cell, the polar axis aligns at some angle to the rubbing direction to mitigate surface electric charge. We demonstrate that the pseudolayers in planar cells form chevron defects, a hallmark defect of one-dimensionally positionally ordered phases, such as smectic A and smectic C. The polar character of the twist-bend axis prevents the cores of NTBF edge dislocations from splitting into semi-integer disclinations, in stark contrast to dislocations in paraelectric and ferroelectric chiral nematics. The tilt of pseudolayers around the defect core allows us to estimate the elastic penetration length as being close to the pitch of NTBF. Compression/dilation stresses around the core modify the heliconical tilt angle of molecules as evidenced by a substantial variation in local birefringence. The climb of dislocations exhibits high mobility, allowing the system to equilibrate the temperature-dependent pitch. The uncovered properties facilitate the development of NTBF materials for electro-optical applications, such as electrically controlled diffraction lattices and structural colors.