Evidence for Anion-Free-Electron Duality and Enhanced Superconducting Role of Interstitial Anionic Electrons in Electrides

TL;DR

This study demonstrates that interstitial anionic electrons in electrides act as dual entities, significantly contributing to superconductivity through electron-phonon interactions, as evidenced by combined experimental and theoretical analyses.

Contribution

It provides direct experimental and theoretical evidence for the dual nature of IAEs and their active role in enhancing superconductivity in electrides, resolving longstanding ambiguities.

Findings

IAEs exhibit dual nature as anions and free electrons.

IAEs originate from states near the Fermi level above potential barriers.

Oxygen treatment reduces IAEs and suppresses superconductivity.

Abstract

The discovery of superconducting electrides, characterized by interstitial anionic electrons (IAEs) residing in lattice cavities, has established a distinctive platform for investigating superconductors. Yet the superconducting origin and the fundamental role of IAEs in Cooper pairing formation remain poorly understood due to the challenges in directly observing IAEs. Here, combining angle-resolved photoemission spectroscopy (ARPES), transport measurements, and first-principles calculations, we certify that the IAEs in electride La3In (Tc = 9.4 K) exhibit a dual nature as both anions and free electrons. With the finite-depth potential well model, we trace that IAEs originate from electronic states near the Fermi level located above potential barriers, forming a Fermi sea susceptible to scattering by La-derived phonons, triggering superconductivity. ARPES combined with high-resolution XRD measurements on oxygen-treated samples directly reveals IAEs' spatial distribution and energy dispersion from interstitial sites with the consistent energy value predicted by our theory model. The concomitant diminution of free electrons upon oxygen treatment, leading to a marked reduction in superconductivity, further provides compelling experimental evidence that IAEs actively participate in electron-phonon coupling. Our findings resolve the long-standing ambiguity regarding the electronic nature of IAEs, elucidate their enhancing superconductivity in the phonon-mediated mechanism, and provide a foundation for exploring advanced electride-based superconductors.