Beyond the Expiry Date: Uncovering Hidden Value in Functional Drink Waste for a Circular Future

TL;DR

This study characterizes expired functional drinks to identify their potential as feedstocks for biomethane production, revealing optimal recovery times and chemical composition changes during deterioration.

Contribution

It provides a comprehensive analysis of the chemical composition and biomethane potential of expired functional drinks, including their dynamic resource variation over time.

Findings

High sugar and organic acid content enable profitable biomethane recovery.

Optimal biomethane production occurs after sorbitol degradation, during natural deterioration.

Expired drinks show distinct phases of resource stability and degradation.

Abstract

Expired functional drinks have great valorisation potential due to the high concentration of organic molecules present. However, detailed information of the resources in these expired functional drinks is limited, hindering the rational design of a recovery system. To address this gap, we present here a study that comprehensively characterises the chemical composition of functional drinks and discus their potential use as feedstocks for biomethane production. The example functional drinks were abundant in sugars, organic acids, and amino acids, and were especially rich in glucose, fructose, and alanine. Our studies revealed that functional drinks with high COD values that corresponded to high proportions of sugar and organic acid and low proportions of sorbitol and amino acids could realise profitable recovery through anaerobic digestion, with a minimum biomethane yield of 11.72 mL CH4 / mL drink. To assess utility further we also examined the dynamic composition of functional drinks up to 16 weeks (at 4 {\deg}C) after expiration to capture the shift in resources during deterioration. In doing so, we identified 4 distinct periods of carbon resource variation: 1) chemically stable period, 2) sorbitol degradation period, 3) sugar degradation period, and 4) acidification period. Based on the time-course biomethane production experiments for expired functional drinks, the optimal operating time window for biomethane production from drinks without ascorbic acid would be after sorbitol degradation period in terms of its economic performance through convenient natural deterioration. Therefore, this comprehensive study on dynamic chemical composition in expired functional drinks and their biomethane production potential could facilitate a rational design of resource recovery system for soft drink field.