Triple point in a cell fluid model with effective temperature-dependent attraction

TL;DR

This paper investigates a cell fluid model with temperature-dependent attraction, revealing that such modifications can introduce a triple point in the phase diagram while maintaining exact solvability.

Contribution

It demonstrates that incorporating effective temperature-dependent attraction in a solvable cell fluid model leads to the emergence of a triple point in the phase diagram.

Findings

Inclusion of temperature-dependent attraction creates a triple point.

The model remains exactly solvable despite modifications.

Phase behavior is significantly altered by temperature-dependent interactions.

Abstract

We study a cell fluid model of a many-particle system with Curie-Weiss-type interaction potential. It is considered as an open system in a fixed volume partitioned into a large number of congruent cubic cells. The interaction potential comprises two competing components: a global uniform attraction acting between all particle pairs in the volume and a short-range repulsion between particles occupying the same cell. Previous studies have established that this model admits an exact solution, exhibits multiple critical points, and undergoes a sequence of first-order phase transitions. Despite variations in the interaction strengths, no triple point appears as long as these parameters remain fixed. We demonstrate that incorporating effective {temperature-dependent} attractive interactions fundamentally alters the phase behavior of the cell model. This modification preserves the model's exact solvability while resulting in the emergence of a triple point in the phase diagram.