Rheological Behavior of Colloidal Silica Dispersion: Irreversible Aging and Thixotropy

TL;DR

This study investigates the aging and thixotropic behavior of colloidal silica dispersions, revealing irreversible aging effects over days and developing a kinetic model to describe their complex rheological properties.

Contribution

It provides new insights into the irreversible aging phenomena in silica dispersions and introduces a thixotropic structural kinetic model within a Maxwell framework.

Findings

Relaxation time increases hyper-linearly with age.

Steady state flow curve exhibits non-monotonic behavior with negative slope.

Physical aging becomes irreversible over long durations due to bond strengthening.

Abstract

In this work, we study the rheological behavior of colloidal dispersion of charge-screened nanoparticles of silica suspended in aqueous media that exhibits soft solid-like consistency. We observe that the system shows various characteristics of physical aging wherein it undergoes time evolution of rheological properties such as elastic modulus, relaxation time, and yield stress subsequent to shear melting of the same. Notably, the relaxation time increases more strongly than linearly with time, which is suggestive of hyper-aging dynamics. When considered along with the time-dependent yield stress, this behavior indicates the steady state shear stress-shear rate flow curve to be non-monotonic with a negative slope in a lower shear rate region. Performing shear melting on this system at a later date since the preparation of the dispersion (rest time) results in higher viscosity as well as yield stress, and the corresponding evolution of the elastic modulus shifts to lower times. This implies that physical aging in studied silica dispersion, while reversible over short time scales (of the order of hours), becomes irreversible over longer durations (days) owing to the inability of strong shear to break interparticle bonds that have strengthened over long durations. We also develop a thixotropic structural kinetic model within a time-dependent Maxwell framework that captures the experimentally observed rheological behavior well.