Lattice dynamics in chiral tellurium by linear and circularly polarized Raman spectroscopy: crystal orientation and handedness

TL;DR

This study uses polarized Raman spectroscopy to analyze the crystal orientation and handedness of trigonal tellurium, revealing how these factors influence its optical and transport properties, and guiding device fabrication.

Contribution

It introduces a method combining angle-dependent and circularly polarized Raman spectroscopy to determine tellurium's crystal orientation and handedness unambiguously.

Findings

Determined the arrangement of helical chains in tellurium.

Identified phonon mode shifts related to crystal handedness.

Highlighted the importance of crystal orientation in property analysis.

Abstract

Trigonal tellurium (Te) has attracted researchers' attention due to its transport and optical properties, which include electrical magneto-chiral anisotropy, spin polarization and bulk photovoltaic effect. It is the anisotropic and chiral crystal structure of Te that drive these properties, so the determination of its crystallographic orientation and handedness is key to their study. Here we explore the structural dynamics of Te bulk crystals by angle-dependent linearly polarized Raman spectroscopy and symmetry rules in three different crystallographic orientations. The angle-dependent intensity of the modes allows us to determine the arrangement of the helical chains and distinguish between crystallographic planes parallel and perpendicular to the chain axis. Furthermore, under different configurations of circularly polarized Raman measurements and crystal orientations, we observe the shift of two phonon modes only in the (0 0 1) plane. The shift is positive or negative depending on the handedness of the crystals, which we determine univocally by chemical etching. Our analysis of three different crystal faces of Te highlights the importance of selecting the proper orientation and crystallographic plane when investigating the transport and optical properties of this material. These results offer insight into the crystal structure and symmetry in other anisotropic and chiral materials, and open new paths to select a suitable crystal orientation when fabricating devices.