The SOMA MM Survey. I. An Astrochemical Census of Massive Protostars

TL;DR

This study analyzes the chemical composition of 22 massive protostars to understand how chemical evolution correlates with physical properties, revealing links between molecular complexity, temperature, and evolutionary stage.

Contribution

It provides the first comprehensive chemical census of massive protostars using ALMA data, identifying correlations between chemical signatures and physical parameters.

Findings

High chemical complexity in some sources with >100 molecular transitions

Correlation between excitation temperature and evolutionary stage

Presence of hot cores with T_ex > 100 K indicating thermal desorption

Abstract

During massive star formation, dense gas undergoes chemical evolution, producing both simple and complex organic molecules (COMs) characteristic of hot molecular cores. How this evolution depends on protostellar physical properties remains unclear. We investigate the chemical content of 22 well-studied massive protostars from the SOFIA Massive (SOMA) Star Formation survey, aiming to identify correlations between chemical and physical parameters. We analyzed Atacama Compact Array and Total Power 1.3 mm (Band 6) data, deriving column densities, line widths, and excitation temperatures of multiple molecular species by modeling detected lines under local thermodynamic equilibrium (LTE) using MADCUBA. Spectra show 35 species, from simple molecules (e.g., CO, SO, SiO) to complex organic molecules (COMs), with seven sources exhibiting high chemical complexity (> 100 transitions). Average excitation temperatures vary across the sample: $T_\text{ex}>100~\text{K}$ for eight sources, $50-100~\text{K}$ for four, and $T_\text{ex} < 50~\text{K}$ for the remainder. Sources with $T_\text{ex} < 50~\text{K}$ trace lukewarm, chemically simple gas, while those with $T_\text{ex}>100~\text{K}$ indicate the presence of typical hot cores where thermal desorption is efficient, resulting in line-rich spectra. Comparing these chemical properties with the bolometric luminosity to envelope mass ratio ($L_\text{bol}/M_\text{env}$), an evolutionary tracer, we find tentative correlations with line widths, excitation temperature, and column densities. These data provide important constraints for chemodynamical models of massive protostellar cores.