Liquid-vapor transition in a model of a continuum particle system with finite-range modified Kac pair potential

TL;DR

This paper proves the existence of a liquid-vapor phase transition in a continuum particle system with a finite-range modified Kac potential, extending previous results and avoiding unphysical interactions.

Contribution

It introduces a new continuum particle model with a modified Kac potential and establishes a first-order phase transition using reflection positivity and Dobrushin--Shlosman criterion.

Findings

Existence of phase transition for small positive gamma

Transition closely related to van der Waals limit

Applicable to general short-range potentials

Abstract

We prove the existence of a phase transition in dimension $d>1$ in a continuum particle system interacting with a pair potential containing a modified attractive Kac potential of range $\gamma^{-1}$, with $\gamma>0$. This transition is "close", for small positive $\gamma$, to the one proved previously by Lebowitz and Penrose in the van der Waals limit $\gamma\downarrow0$. It is of the type of the liquid-vapor transition observed when a fluid, like water, heated at constant pressure, boils at a given temperature. Previous results on phase transitions in continuum systems with stable potentials required the use of unphysical four-body interactions or special symmetries between the liquid and vapor. The pair interaction we consider is obtained by partitioning space into cubes of volume $\gamma^{-d}$, and letting the Kac part of the pair potential be uniform in each cube and act only between adjacent cubes. The "short-range" part of the pair potential is quite general (in particular, it may or may not include a hard core), but restricted to act only between particles in the same cube. Our setup, the "boxed particle model", is a special case of a general "spin" system, for which we establish a first-order phase transition using reflection positivity and the Dobrushin--Shlosman criterion.