Extinction Coefficients of CdSe, CdS, and CdTe Nanoplatelets in Solution: A Practical Tool for Concentration Determination

TL;DR

This paper introduces a theoretical model that predicts the absorption coefficients of CdSe, CdS, and CdTe nanoplatelets, enabling quick concentration and size estimation from optical measurements, thus simplifying nanoplatelet characterization.

Contribution

The study provides a validated theoretical framework linking absorption coefficients to nanoplatelet size and concentration, reducing reliance on elemental analysis techniques.

Findings

Universal dependence of absorption on surface area and thickness

Model accurately predicts absorption spectra for different nanoplatelet types

Enables rapid concentration determination from optical data

Abstract

Semiconductor nanoplatelets possess exceptional optical properties that make them promising candidates for next-generation optoelectronic applications. However, unlike quantum dots where absorption spectroscopy alone can determine both size and concentration, nanoplatelets present a significant characterization challenge: the absorption peak position reveals only thickness, providing no information about lateral dimensions or concentration. This limitation forces researchers to rely on time-consuming and costly elemental analysis techniques for complete sample characterization. Here, we present an experimentally verified theoretical framework that predicts the frequency-dependent absorption coefficient of randomly oriented CdSe, CdS, and CdTe nanoplatelets, enabling concentration determination from absorption measurements and lateral size estimates. Our model shows that the integrated absorption coefficient depends universally on nanoplatelet surface area and thickness, yielding a practical tool to extract concentrations without laborious elemental analysis. This approach bridges the characterization gap between quantum dots and nanoplatelets, offering a streamlined method for rapid sample analysis that could accelerate nanoplatelet research and applications.