Optimization of superconducting properties of F-doped SmFeAsO by cubic anvil high-pressure technique

TL;DR

This study optimizes high-pressure synthesis of F-doped SmFeAsO superconductors, demonstrating improved critical current density and transition temperature, while highlighting persistent impurity phases despite various pressure techniques.

Contribution

It introduces optimized in-situ high-pressure synthesis conditions that enhance superconducting properties of SmFeAsO, with detailed comparison to other methods.

Findings

In-situ process at 4 GPa and 1400°C improves Jc and Tc.

Ex-situ process enhances Jc but not Tc.

Impurity phases persist across all pressure techniques.

Abstract

We optimize the synthesis conditions for SmFeAsO0.80F0.20 (Sm1111) bulks using a cubic-anvil high-pressure (CA-HP) apparatus through both ex-situ and in-situ processes, applying pressures of up to 4 GPa and heating temperatures of up to 1600{\deg}C. A comprehensive characterization has been performed, including structural, microstructural, transport, and magnetic measurements. Our findings indicate that a modest growth pressure of approximately 0.5 GPa is sufficient for the formation of the Sm1111 phase in the ex-situ process. In contrast, the in-situ process requires higher synthesis pressure (4 GPa) and temperature (1400 {\deg}C for 1 hour) to achieve the Sm1111 phase with enhanced superconducting properties. Notably, the optimized in-situ process significantly reduces the reaction time needed for the formation of the Sm1111 phase compared to conventional synthesis process at ambient pressure (CSP), leading to an increase in the transition temperature by 3 K and improvements in critical current density (Jc). Conversely, the optimized ex-situ process results in an onset transition temperature (Tc) of approximately 53 K, similar to that of CSP, though it enhances the Jc by an order of magnitude. Despite these advancements, a small amount of impurity phases, as observed during CSP, persists in all Sm1111 samples prepared through either the in-situ or ex-situ CA-HP processes. These results suggest that the in-situ process under optimized conditions (1400 {\deg}C, 4 GPa for 1 hour) can effectively improve the superconducting properties of Sm1111. Additionally, a comprehensive analysis comparing these results with high gas pressure techniques, spark plasma sintering, and CSP methods suggests that a small amount of impurity phases in Sm1111 is persistent and cannot be completely eliminated by various pressure techniques, even at the applied pressure of up to 4 GPa.