Influence of local strain on the optical probing of a Ni$^{2+}$ spin in a charged self-assembled quantum dot

TL;DR

This paper investigates how local strain affects the optical properties and spin states of Ni$^{2+}$ ions in charged quantum dots, revealing strain-dependent spin configurations and exchange interactions through magneto-optical analysis.

Contribution

It introduces a spin-effective model incorporating local strain orientation to accurately reproduce experimental optical spectra and spin behavior in Ni$^{2+}$ doped quantum dots.

Findings

Strain distribution significantly influences Ni$^{2+}$ spin states.

In-plane biaxial strain allows observation of specific Ni$^{2+}$ spin states.

Low-symmetry strain mixes all Ni$^{2+}$ spin states, increasing optical transitions.

Abstract

This study explores the optical properties of quantum dots doped with a Ni$^{2+}$ ion that interacts with a charged exciton. Systematic magneto-optical analysis reveals that the strain distribution at the Ni$^{2+}$ site significantly influences its spin structure. In positively charged dots dominated by in-plane biaxial strain, the three spins states of the Ni$^{2+}$ (S$_z$=0, S$_z$=$\pm$1) can be observed and the magneto-optical spectra enables a local strain anisotropy to be determined. However, in most of the dots, lower-symmetry strain mixes all the Ni$^{2+}$ spin states, thereby increasing the number of observed optical transitions. In charged dots, we identify optical transitions that share a common excited state. They form a series of $\Lambda$ levels systems that can be individually addressed optically to determine the energy level structure. Magneto-optical measurements demonstrate that the hole-Ni$^{2+}$ exchange interaction is antiferromagnetic and considerably stronger than the electron-Ni$^{2+}$ interaction. A spin-effective model that incorporates local strain orientation can successfully reproduce key experimental results. Furthermore, we demonstrate that low-symmetry terms in the hole-Ni$^{2+}$ exchange interaction must be considered in order to accurately describe the emission spectra details in a magnetic field.