Isolated spin ladders in Ln$_2$Ti$_9$Sb$_{11}$ (Ln:La-Nd) metals

TL;DR

This paper reports the discovery of Ln$_2$Ti$_9$Sb$_{11}$ compounds with isolated rare-earth spin ladders, revealing diverse magnetic behaviors and potential for tunable magnetic states in an inorganic square spin-ladder system.

Contribution

It introduces a new series of compounds with well-isolated rare-earth spin ladders and characterizes their structural, electronic, and magnetic properties, highlighting their tunability and rich magnetic phenomena.

Findings

Nd$_2$Ti$_9$Sb$_{11}$ and Ce$_2$Ti$_9$Sb$_{11}$ show antiferromagnetic interactions.

Pr$_2$Ti$_9$Sb$_{11}$ has a weakly magnetic singlet ground state.

Nd$_2$Ti$_9$Sb$_{11}$ is a poor metal with resistivity 0.1mΩ·cm at 300K.

Abstract

Here we present the discovery and characterization of a series of antimonides Ln$_2$Ti$_9$Sb$_{11}$ (Ln: La--Nd) which exhibit well-isolated, $n=2$ rare-earth spin ladders. We discuss the structure of the new compounds, with a particular focus on the magnetic Ln spin ladders. Nd$_2$Ti$_9$Sb$_{11}$ and Ce$_2$Ti$_9$Sb$_{11}$ exhibit antiferromagnetic interactions and a well-defined doublet ground state, whereas Pr$_2$Ti$_9$Sb$_{11}$ exhibits a weakly magnetic singlet ground state. Nd$_2$Ti$_9$Sb$_{11}$ is a poor metal with an electrical resistivity of 0.1m$\Omega$-cm at 300K and weak temperature dependence. The thermal conductivity along the ladder exhibits significant field dependence even at 40K, considerably higher than the magnetic ordering temperature of 1.1K. Compared to compounds with transition metal spin ladders, the rare-earth elements impart much lower energy scales, making these compounds highly tunable with external stimuli like magnetic fields. The diverse magnetism of the rare-earth ions and RKKY interactions further contribute to the potential for a wide array of rich magnetic ground states, positioning these materials as a rare example of an inorganic square spin-ladder platform.