Direct Measurement of the Effective Electronic Temperature in Organic Semiconductors

TL;DR

This paper directly measures the effective electronic temperature in organic semiconductors using nanoscopic devices, confirming theoretical predictions and suggesting potential for thermoelectric applications.

Contribution

It provides the first direct experimental measurement of the effective electronic temperature in organic semiconductors, validating kinetic Monte Carlo models.

Findings

Measured Seebeck voltage indicating increased T_eff

Quantitative agreement with kinetic Monte Carlo simulations

Implications for low-loss thermoelectric devices

Abstract

Organic semiconductors show complex phenomena due to their high energetic disorder. A striking example is the possibility of an increased effective temperature T_eff of the charge carrier distribution relative to the lattice temperature, which results from the slow charge carrier relaxation after excitation, either by high electric field or photon absorption. The increased effective temperature has been linked to conductivity enhancements and performance increases in actual devices, but a direct observation has been lacking. Here, we utilize nanoscopic tree-terminal devices to measure the Seebeck voltage arising in a doped organic polymer semiconductor due to a field-driven enhancement of the effective electronic temperature, providing direct proof of the existence of T_eff. The results agree quantitatively with numerical predictions by a kinetic Monte Carlo model. The findings not only provide fundamental understanding but also indicate an avenue towards low-loss thermoelectric devices.