Superconducting coherence boosted by outer-layer metallic screening in multilayered cuprates

TL;DR

This study demonstrates that outer-layer metallic screening in multilayered cuprates enhances superconductivity by isolating a clean CuO2 layer, leading to unprecedented superconducting properties and providing new insights into the interplay between disorder, pseudogap, and superconductivity.

Contribution

It reveals that outer-layer metallic screening isolates a superconducting CuO2 layer, significantly boosting its superconducting gap and coherence, a novel physical mechanism in cuprate superconductors.

Findings

Inner CuO2 planes become superconducting while outer layers remain metallic.

The isolated CuO2 layer exhibits the largest known superconducting gap in cuprates.

A coherent flat band at the Brillouin zone edge overcomes pseudogap damping.

Abstract

In multilayered high-Tc cuprates with three or more CuO2 layers per unit cell, the inner CuO2 planes (IPs) are spatially separated from the dopant layers and thus remain cleaner than the outer planes (OPs). While both interlayer coupling and the presence of clean IPs have been proposed as key factors enhancing superconductivity, their individual roles have been difficult to disentangle, as IPs and OPs typically become superconducting simultaneously. Here we investigate five-layer (Cu,C)Ba2Ca4Cu5Oy (Cu1245) with Tc = 78 K and three-layer Ba2Ca2Cu3O6(F,O)2 (F0223) with Tc = 100 K using ARPES, and uncover an unprecedented situation, in which only the IPs become superconducting while the OPs remain metallic at low temperatures. Model calculations indicate that more than 95% of the OP wavefunction remains confined to OP itself, with minimal hybridization from the superconducting IPs. In particular, we experimentally realize an ideal configuration: a single superconducting CuO2 layer sandwiched between heavily overdoped metallic outer layers, which screen disorder originating from the dopant layers. Strikingly, this clean CuO2 layer exhibits the largest superconducting gap among all known cuprates and coherent Bogoliubov peaks extending beyond the antiferromagnetic zone boundary -- long regarded as the boundary beyond which coherence vanishes in heavily underdoped cuprates. Furthermore, a widely extended coherent flat band emerges at the Brillouin zone edge, overcoming the pseudogap damping effect. Our results introduce a new physical parameter, the degree of screening, to investigate the competition between superconductivity and the pseudogap, potentially shedding new light on its origin. The nearly disorder-free superconducting CuO2 layers offer a model platform for bridging the gap between disordered real materials and idealized theoretical models, which generally neglect disorder effects.