Exploiting solute segregation and partitioning to the deformation-induced planar defects and nano-martensite in designing ultra-strong Co-Ni base alloys

TL;DR

This paper demonstrates how atomic-scale solute interactions and controlled thermomechanical processing can create ultra-strong Co-Ni alloys with yield strengths exceeding 2 GPa, while maintaining ductility and high-temperature stability.

Contribution

It introduces a novel approach to alloy design by exploiting solute segregation to deformation-induced structures to significantly enhance strength.

Findings

Achieved yield strength > 2 GPa in Co-Ni alloys.

Controlled processing scales microstructure strengthening.

Alloy microstructure remains stable at high temperatures.

Abstract

Single-phase, multi-elements (three or more) with high concentrations show exceptional tensile strength up to ~ 0.8-1.2 GPa. However, they possess a very low 0.2% yield strength (YS), i.e., they can be permanently deformed at very low-stress levels of 300 to 600 MPa. Here, we reveal by exploiting atomic-scale solute interactions with the deformation-induced structures to design ultra-strong single-phase alloys with YS > 2 GPa. This was achieved by controlled thermomechanical processing that introduces stacking-faults (SFs), nano-twins (NTs), and nano-martensite {\epsilon}-laths (NMLs) during cold deformation followed by facilitating solute segregation/partitioning to them by tempering at intermediate temperature. We demonstrate the phenomena in a low stacking faulty energy multi-component (face-centered-cubic, fcc structured) Co-33Ni-24Cr alloy (all in at.%) containing 5at.% Mo as a solute. It is also shown that the degree of strengthening after tempering scales up with the fraction of these structures (before tempering) in the alloy microstructure that can be tuned by the amount and temperature of cold deformation. Cold-rolling with 45% and 65% thickness reduction, followed by tempering at 600{\deg}C for 4 hours, led to an YS of 1.5 GPa and 2 GPa with elongation to fracture (%El) 14% and 7%, respectively. The YS is further enhanced to ~ 2.2 GPa without reduction in %El upon cryo-rolling followed by tempering. The alloy microstructure is stable at 600{\deg}C up to 100 hours and also retains an YS of ~ 1.5 GPa with %El of 18% during tensile test at 600{\deg}C. The derived high YS and high-temperature stability are critically a consequence of solute partitioning to the NMLs that we termed as Solute-Partitioned NMLs (SP-NMLs) in the microstructure.