X-ray Emission Spectropolarimetry of Strongly Anisotropic Single Crystal Systems using a Rowland Circle Geometry

TL;DR

This paper demonstrates how a Rowland circle geometry can be used as a spectropolarimeter to analyze polarized x-ray emission from strongly anisotropic single crystal systems, revealing detailed electronic and orbital information.

Contribution

It introduces a novel application of the Rowland circle geometry for polarized x-ray emission spectropolarimetry of transition metal systems, expanding the analytical capabilities of x-ray spectroscopy.

Findings

Polarized x-ray emission provides insights into valence electron orbitals.

The method can distinguish between core-to-core and valence-to-core emissions.

Polarized spectra can be extracted with high angular resolution.

Abstract

Polarization dependence has historically seen extensive use in x-ray spectroscopy to determine magnetic and local geometric properties, but more broadly as a way to gain extra sensitivity to electronic structure at the level of individual magnetic orbitals. This is often done in the context of x-ray absorption through techniques like x-ray magnetic circular dichroism or x-ray linear dichroism, but it has seen little application to x-ray emission. Here we explore the information contained in the polarized emission of two 3d transition metal systems across both core-to-core (CtC) and valence-to-core emission (VtC) lines. We demonstrate how the Rowland circle geometry can be used as a spectropolarimeter, and apply it to the x-ray emission spectroscopy of spin-1/2 Cu(II) and spin-0 Ni(II) ions in LiVCuO4 and DyNiC2, respectively. From this we explore how the polarized XES interrogates of the occupied density of states at the valence level, either as a second order effect through Coulomb exchange (CtC x-ray emission) or by direct transitions (VtC x-ray emission). We find that the polarized x-ray emission can provide insights into the valence electron orbital occupation, in much the same way that is achievable with polarized absorption or angle-resolved photoemission spectroscopy techniques. Finally, we highlight how the individually polarized dipole emission spectra can be extracted from a linearly independent suite of directed emission spectra, allowing for polarized measurements at high Bragg angle with lower experimental broadening.