A Study of Non-linear Flows and Shear Banding in Wormlike Micelles Under Varying Elasticity, Flow Curvature, and Surfactant Chemistry

TL;DR

This study investigates how surfactant chemistry, elasticity, and flow curvature influence shear-banding and flow dynamics in wormlike micellar solutions within a Taylor-Couette setup, revealing critical thresholds for flow reversal and slip behavior.

Contribution

It provides a systematic analysis of the effects of elasticity number, flow curvature, and surfactant chemistry on flow heterogeneities and shear banding in wormlike micelles.

Findings

Stress overshoot increases with elasticity and curvature.

Flow reversal occurs in CTAB/NaSal but not in CPyCl/NaSal solutions.

Wall slip shows non-monotonic dependence on flow parameters.

Abstract

We report the flow dynamics of two shear-banding wormlike micellar solutions with distinct surfactant chemistries in a Taylor-Couette (TC) setup following a startup shear. The solutions, formulated with CTAB/NaSal and CPyCl/NaSal, exhibit comparable bulk rheology and equilibrium microstructural properties. By varying the TC gap size, we systematically examine elasticity number over a range of 128000-4470000, while flow curvature spans from 0.022 to 0.171. Under a step shear into the stress plateau, both solutions exhibit a pronounced stress overshoot that intensifies with increasing elasticity number and flow curvature, followed by the development of growing flow heterogeneities. Beyond a critical threshold of elasticity number and curvature, the CTAB/NaSal solution exhibits transient flow reversal, whereas the CPyCl/NaSal solution, despite developing similar heterogeneities, does not undergo flow reversal under any tested conditions. We hypothesize that this difference arises from the stronger electrostatic repulsions between CPyCl head groups due to their larger size, coupled with the higher dissociation rate of Cl counterions. Additionally, the quasi-steady velocity profiles are significantly influenced by elasticity number and flow curvature. Wall slip at the outer cylinder exhibits a non-monotonic dependence on these parameters: it is negligible at low values of elasticity number and flow curvature, peaks at intermediate values, and diminishes at high values. Our findings highlight how surfactant chemistry, elasticity number, and flow curvature control shear-banding flows in wormlike micelles.