From Bulk to Nanowire: A Dimensional Journey with CeIn$_3$

TL;DR

This study synthesizes CeIn$_3$ nanowires using a metallic-flux nanonucleation method and investigates how reduced dimensionality affects their magnetic and structural properties, revealing suppressed magnetic ordering and increased frustration.

Contribution

It introduces a novel synthesis approach for CeIn$_3$ nanowires and systematically analyzes the effects of nanoscale dimensions on their magnetic and structural behavior.

Findings

Nanowires are polycrystalline with ~170 nm diameter.

Antiferromagnetic transition temperature is reduced to ~2.4 K.

Evidence of increased magnetic frustration in nanowires.

Abstract

In this work, we have explored the Metallic-Flux Nanonucleation method to synthesize single crystals and nanowires (diameter $\approx$ 170 nm) of CeIn$_{3}$ and compare their properties. The effects of reduced dimensionality were systematically investigated using Energy Dispersive Spectroscopy (EDS), Selected area electron diffraction (SAED), magnetic susceptibility, heat capacity, and Nuclear Magnetic Resonance (NMR). Semi-quantitative EDS analysis revealed a Ce:In ratio of 1:3.1(1), and the SAED results confirmed that the nanowires are polycrystalline with a cubic unit cell. Magnetic susceptibility, specific heat, and NMR data indicated a suppression of the antiferromagnetic transition to $T_N$ $\approx$ 2.4 K compared to the bulk value ($\approx$ 10 K). Furthermore, NMR analysis at temperatures below 2.8 K showed a reduced quadrupole frequency, $\nu_Q$ $\approx$ 1.77(2) MHz, and provided evidence of polycrystalline nanowires formed within the nanoporous alumina template, in agreement with SAED results. We attribute these findings to an increasing magnetic order frustration induced by dimensionality in CeIn$_{3}$ nanowires.