Magnetocalorics of singlet ground state induced moment magnets

TL;DR

This paper explores the magnetocaloric effects in singlet ground state induced moment magnets, focusing on quantum criticality, specific heat behavior, and excitation spectra in f-electron compounds like PrIr3.

Contribution

It provides a detailed analysis of the magnetocaloric properties and excitation spectra of singlet ground state induced moment magnets, highlighting the effects of external fields and temperature.

Findings

Entropy release is due to competition between thermal depopulation and spontaneous order.

Critical soft mode exists only at specific phase diagram points.

Field and temperature dependence of specific heat are characterized.

Abstract

In f-electron materials like Pr or U compounds with non-Kramers states of the f-shell the ground state may be a nonmagnetic singlet due to the action of the crystalline electric field. Nevertheless these compounds can order magnetically. They develop a ground state moment and long range order due to the spontaneous admixture of the excited state into the ground state caused by inter-site exchange. This mechanism can establish magnetic order if a control parameter exceeds a critical value defining the quantum critical point between disordered and magnetic phase. Here we investigate the magnetocaloric properties of such quantum magnets where the entropy release at low temperature is due to a competition between thermal depopulation and spontaneous order effects. We determine field and temperature dependence of specific heat for ferro- and antiferromagnetic order and also calculate the adiabatic magneto- and barocaloric cooling rates. As a model application we discuss the magnetic specific heat of the new induced ferromagnet PrIr3. Furthermore we analyze the excitation spectrum of the singlet induced moment magnets in an external field with particular emphasis on field and temperature dependence of the critical soft mode. We find that the latter is fragile and exists only at specific points in the phase diagram.