Nonlinear ferroelectric characteristics of barium titanate nanocrystals determined via a polymer nanocomposite approach

TL;DR

This study introduces a polymer nanocomposite method to accurately measure the nonlinear ferroelectric properties of barium titanate nanocrystals, revealing size-dependent ferroelectric behavior.

Contribution

It presents a novel approach to extract polarization-electric field loops of ferroelectric nanocrystals from polymer composites, enabling detailed analysis of their nonlinear characteristics.

Findings

BTO380 nanocrystals show square-shaped ferroelectric loops.

BTO60 nanocrystals display slim paraelectric loops.

The method accurately estimates dielectric constants and internal fields of nanocrystals.

Abstract

The growing demand for high energy storage materials has garnered substantial attention towards lead-free ferroelectric nanocrystals (NCs), such as BaTiO3 (BTO), for next-generation multilayer ceramic capacitors. Notably, it remains challenging to accurately measure the dielectric constant and polarization-electric field (P-E) hysteresis loop for BTO NCs. Herein, we report on nonlinear ferroelectric characteristics of BTO NCs via a polymer nanocomposite approach. Specifically, poly(vinyl pyrrolidone)(PVP)/BTO nanocomposite films of 3-10 {\mu}m thickness, containing 380 nm tetragonal-phased and 60 nm cubic-phased BTO NCs with uniform particle dispersion, were prepared. Theoretical deconvolution of the broad experimental P-E loops of the PVP/BTO NC composite films revealed three contributions, that is, the linear deformational polarization of the nanocomposites, the polarization of BTO NCs (Pp ), and the polarization from strong particle-particle interactions. Using different mixing rules and nonlinear dielectric analysis, the overall dielectric constants of BTO NCs were obtained, from which the internal field in the BTO NCs (Ep ) was estimated. Consequently, the Pp-Ep hysteresis loops were obtained for the BTO380 and BTO60 NCs. Interestingly, BTO380 exhibited square-shaped ferroelectric loops, whereas BTO60 displayed slim paraelectric loops. This work presents a robust and versatile route to extract the Pp-Ep loops of ferroelectric NCs from polymer/ceramic nanocomposites.