Importance of anisotropic interactions for hard-axis/plane ordering of Ce-based ferromagnets

TL;DR

This study investigates the magnetic ordering directions in Ce-based ferromagnets, revealing that most prefer easy-axis/plane alignment and that anisotropic exchange interactions, rather than Kondo effects, primarily influence this behavior.

Contribution

The paper provides a comprehensive survey and analysis showing that hard-axis/plane ordering is less common than previously thought, emphasizing the role of exchange anisotropy over Kondo effects.

Findings

Most Ce-based ferromagnets order along their easy-axis/plane.

No clear correlation between Kondo strength and ordering direction.

Antiferromagnetic interactions along the easy-axis can stabilize hard-axis ferromagnetic order.

Abstract

Ferromagnetic (FM) Kondo-lattice (KL) compounds often exhibit intriguing magnetic behavior driven by strong crystal electric field (CEF) anisotropy and exchange interactions. Recent studies suggest that many Ce-based and Yb-based KL ferromagnets order along the hard-axis or hard-plane determined by their CEF ground state. We performed a survey of Ce-based FM compounds, complemented with new single crystal synthesis, magnetization measurements, and analysis of the CEF scheme. Our results reveal that hard-axis/plane ordering is less common than previously reported, with most compounds ordering along their easy-axis/plane. We also find no clear correlation between the strength of the Kondo effect and whether a compound adopts hard-axis/plane or easy-axis/plane ordering. Instead, the key driver appears to be the competition between CEF anisotropy and exchange interaction anisotropy. A direct comparison of CeCuSi and CeAgSb$_2$ further indicates that antiferromagnetic (AFM) interactions along the CEF easy-axis can be crucial in stabilizing the hard-axis FM ordering observed in CeAgSb$_2$. Finally, our results suggest that an anisotropic Ruderman-Kittel-Kasuya-Yosida (RKKY) model could offer deeper insights into the complicated magnetic properties of Ce-based and other heavy-fermion systems.