Unconventional Spintronics from Chiral Perovskites

TL;DR

This paper explores the electronic and optical properties of chiral perovskites, revealing their potential for unconventional spintronic applications through first-principles calculations and symmetry analysis.

Contribution

It provides a detailed electronic structure and symmetry-based analysis of chiral perovskites, proposing their use in spintronics without net magnetization.

Findings

Chiral perovskites support spin-polarized carriers via CISS.

Effective Hamiltonian explains the origin of chirality.

Optical properties suggest potential for tunable altermagnets.

Abstract

Spintronic devices typically employ heterostructures with ferromagnets which break time-reversal symmetry and have non-vanishing magnetization. With the growing class of materials that support spin-polarized carriers, current, and excitations,it is possible to envision emerging spintronic applications that are not limited to magnetoresistance. Here we focus on chiral perovskites with no net magnetization where the space-inversion and mirror symmetries are broken to induce chiral structure. The known importance of these perovskites is further expanded by the demonstration of the chiral-induced spin selectivity (CISS). However, the generation of the spin-polarized carriers across the interface with these chiral perovskites remains to be fully understood. Our first-principles studies for two-dimensional PbBr$_4$-based chiral perovskites provide their electronic structure and an orbital-based symmetry analysis, which allows us to establish an effective Hamiltonian to elucidate the underlying origin of their chirality. We also use this analysis for the Edelstein effect, responsible for electrical generation of the nonequilibrium spin polarization in many materials, which in chiral perovskites could be a mechanism contributing to CISS. Furthermore, by examining optical properties of chiral perovskites and the opportunity to use them to realize tunable altermagnets, another class of zero-magnetization spintronic materials, we put forth a versatile materials platform for unconventional spintronics.