Passive radiative cooling using temperature-dependent emissivity can sometimes outperform static emitters

TL;DR

This paper introduces a temperature-dependent emissivity emitter that switches between selective and broadband states, potentially outperforming static emitters in passive radiative cooling by maintaining high cooling power across temperatures.

Contribution

It proposes a novel temperature-tunable emitter using VO$_2$ phase transition, enhancing passive cooling efficiency over static emitters across varying temperatures.

Findings

The proposed emitter can switch emissivity states based on temperature.

VO$_2$ phase transition enables tunable emissivity in the atmospheric window.

Potential for improved passive cooling performance across temperature ranges.

Abstract

In passive sky-facing radiative cooling, wavelength-selective thermal emitters in the atmospheric transparency window of 8-13 $\mu$m can reach lower temperatures compared to broadband emitters, but broadband emitters always have higher cooling power when the emitter is warmer than the ambient. Here, we propose a temperature-tunable thermal emitter that switches between a wavelength-selective state -- with high emissivity only in the atmospheric transparency window of 8-13 $\mu$m -- and a broadband-emissive state with high emissivity in the 3-25 $\mu$m range, thus maintaining high cooling potential across all temperatures. We also propose a realization of such a temperature-tunable emitter using the phase transition of vanadium dioxide (VO$_2$), which can be tuned to the ambient temperature using a combination of doping and defect engineering.