XRISM insights for interstellar Sulfur

TL;DR

This study uses XRISM's high-resolution X-ray spectroscopy to detect and analyze interstellar sulfur in gas and solid form, providing new insights into sulfur depletion and dust composition in the Milky Way.

Contribution

First demonstration of interstellar SII K-beta detection in X-ray spectra, and measurement of sulfur depletion and dust composition using XRISM data.

Findings

Detected interstellar SII K-beta absorption in X-ray binaries.

Measured sulfur depletion in the ISM to be 40% +/- 15%.

Found solid sulfur in dust, consistent with Fe-S compounds.

Abstract

The X-ray Imaging Spectroscopy Mission (XRISM) provides the best spectral resolution with which to study Sulfur (S) K-shell photoabsorption features from the interstellar medium (ISM). For the first time, we demonstrate the high-signal detection of interstellar atomic SII K-beta absorption in the spectrum of X-ray binaries (XRBs) 4U 1630-472 and GX 340+0. The persistence of this feature across multiple instruments, targets, and flux states implies that it is interstellar in nature. We measure the SII Kbeta line centroid at 2470.8 +/- 1.1 eV after including systematic uncertainties. We also find that the most recently published high resolution SII absorption template requires a systematic energy scale shift of +7-8 eV, which is comparable to the level of disagreement among various atomic modeling procedures. The XRISM 300 ks observation of GX 340+0 provides unprecedented signal-to-noise in the S K region, and we find evidence of residual absorption from solid S in the spectra of GX 340+0. Absorption templates from three Fe-S compounds, troilite (FeS), pyrrhotite (Fe_7S_8) and pyrite (FeS_2), provide equally good fits to the residuals. Even though we are not able to distinguish among these three compounds, they provide equal estimates for the abundance of S locked in dust grains. Having accounted for both the gaseous and solid S in the GX 340+0 sightline provides us with a direct measurement of S depletion, which is 40% +/- 15%. Our depletion measurement provides an upper limit to the fraction of interstellar Fe bound in Fe-S compounds of < 25%, which is consistent with prior studies of Fe-S compounds via Fe L-shell absorption. Both XRBs in this study are at a distance of approximately 11 kpc and on the opposite side of the Galactic disk, suggesting that this value could represent the average S depletion of the Milky Way when integrated across all phases of the ISM.